Diffusiophoresis in suspensions of highly charged soft particles

Diffusiophoresis phenomenon of aoft particles suspended in binary electrolyte solutions is explored theoretically in this study based on the spherical cell model, focusing on the chemiphoresis component in absence of diffusion potential. Both the electrostatic and hydrodynamic aspects of the boundary confinement, or steric effect, due to the presence of neighboring particles are examined extensively under various electrokinetic conditions. Significant local extrema are found in mobility profiles expressed as functions of the Debye length in general, synchronized with the strength of the motion-inducing double layer polarization. Moreover, a seemingly peculiar phenomenon is observed that the soft particles may move faster in more concentrated suspensions. The competition between the simultaneous enhancement of the motion-inducing electric driving force and the motion-retarding hydrodynamic drag force from the boundary confinement effect of the neighboring particles is found to be responsible for it. The above findings are also demonstrated experimentally in a very recent study on the diffusiophoretic motion of soft particles through porous collagen hydrogels. The results presented here are useful in various practical applications of soft particles like drug delivery.     

反式钙钛矿电池超薄空穴传输层研究进展

空穴传输层(HTLs)厚度对反式钙钛矿太阳能电池(PSCs)性能具有重大影响,因其显著影响太阳光透过和HTLs的空穴传输性能。几个纳米至十几个纳米厚度的超薄HTLs在减少伴生吸收、电荷传输损失和材料消耗等方面具有明显优势。目前,有许多成熟的制备超薄无机HTLs的方法,并在反式和叠层PSCs中得到广泛研究与应用。最近,一些关于有机超薄HTLs的新型制备方法也展现出良好的性能并逐渐引起相关领域研究者关注。在此,本文主要总结反式PSCs中超薄HTLs的研究进展与应用,关注其未来发展的挑战和方向,为该领域进一步的研究提供参考。     

分散溶剂对PEMFC催化层中超薄Nafion离聚物质子传导的影响

质子交换膜燃料电池(PEMFC)商业化应用的瓶颈仍然是贵金属催化剂导致的成本问题。然而,目前对于催化层中纳米尺度全氟磺酸离聚物(以Nafion为代表)薄膜中质子传导的问题研究不足,无法完善三相界面的成型规律,进而指导催化层设计。在催化层浆料制备过程中,分散溶剂对Nafion的分散形态有直接影响,可能对催化层成型后附着在催化剂颗粒表面Nafion薄膜的微观结构有潜在影响,进而影响Nafion薄膜的质子传导能力。因此,在本文中利用分子自组装技术模拟催化层离聚物薄膜的聚集过程,于模型基底上制备厚度精确可控的纳米尺度Nafion薄膜,并通过微观测试表征技术探索并建立纳米尺度Nafion离聚物的微观结构模型,阐明分散溶剂对Nafion薄膜微观结构及质子传导的影响。研究发现Nafion薄膜在纳米尺度下的质子电导率比体相膜的质子电导率低一个数量级,使用介电常数较小的醇类溶剂可以使Nafion薄膜形成更有利于质子传导的微观结构,使Nafion薄膜的质子电导率得到提高。相关研究结果为优化PEMFC催化层结构,改善PEMFC催化层中质子传导问题提供给了依据。     

基于光纤智能夹层传感结构的应力测量研究

制作了一种模块化的光纤传感夹层,对夹层内的光纤传感器的应力特性进行了实验研究。分析了应变对传感系数的影响,对埋入到光纤智能夹层中的两种光纤传感器的输出特性进行了比较。实验结果表明:光纤Bragg光栅传感器的波长漂移与应变之间具有理想的线性关系,但应变灵敏度由1.2pm/με降至1.15pm/με;由于制作工艺的局限,对于非本征F-P光纤传感器,当应变达到350με后,应变与载荷具有较好的线性响应。与非本征F-P光纤传感器相比,光纤Bragg光栅传感器是光纤智能夹层首选的应变传感器。将埋入了Bragg光栅传感器的智能夹层粘贴于某型飞机的翼-身连接构件内部进行监测,实验结果为光纤智能夹层应用于复合材料结构的应变监测提供了参考。     

粘性可压混合层时间稳定性对称紧致差分求解

基于可压扰动方程组的一阶改型 ,将高精度对称紧致格式引入边值法数值线性稳定性分析。对所获非线性离散特征值问题给出了一个通用形式二阶迭代局部算法 ,实现了时间模式和空间模式的统一求解 ,并将扰动特征值及其特征函数同时得到。据此分析了可压平面自由混合层时间稳定性 ,涉及二维 /三维扰动波、粘性 /无粘扰动波、第一 /第二模态、特征函数、伪特征值谱等。研究表明 ,压缩性效应和粘性效应对最不稳定扰动波数和增长率呈相似的减抑作用 ;在 Mc=1附近 ,从高波数段开始 ,粘性效应可强化二维不稳定扰动波由第一模态向第二模态的过渡     

Numerical Modeling of the Development of a Streaky Structure in a Boundary Layer at a High Freestream Turbulence Level

The disturbances generated by external turbulence in the boundary layer on a flat plate set suddenly in motion are determined. A turbulent flow calculated by direct numerical simulation is taken as the initial conditions. The solution obtained simulates the initial stage of laminar-turbulent transition in the flat-plate boundary layer at a high turbulence level in the oncoming flow. The solution makes it possible to estimate the effects of different factors, such as nonstationarity, nonlinearity, and the parameters of the freestream velocity fluctuation spectrum, on disturbance enhancement in the boundary layer.     

On the application of boundary layer method in the large deflection plastic buckling of a cylindrical shell

Using a cylindrical shell under axial loading as an example, we discuss the possibility of applying the membrane theory together with the boundary layer correction to analyze the large deflection plastic buckling problem. In the cases of fixed ends and simply-supported ends, the conditions to be satisfied for using the boundary layer method (also called the composite-expansion method) are given and discussed.     

Mathematical modeling of two problems of wave dynamics in heterogeneous media

Two problems of heterogeneous media mechanics are investigated in the paper. The first one, concerned with the shock wave/dust layer interaction, is solved within the framework of the equilibrium model of heterogeneous media mechanics. The second problem deals with the simulation of a Riemann problem for a stratified layer of solid particles.This paper is based on work that was presented at the 20th International Colloquium on the Dynamics of Explosions and Reactive Systems, Montreal, Canada, July 31–August 5, 2005     

Minimization of the Wing Airfoil Drag Coefficient Using the Optimal Control Method

The problem of designing a wing airfoil starting from the surface velocity (or pressure) distribution, given in multi-parameter form, is considered. In the diffuser region, the velocity decrease law is determined from the conditions of minimum drag and separationless flow for a given Reynolds number. The case of boundary layer suction for the purpose of improving the aerodynamic characteristics of the airfoil is studied. A solution is obtained using optimal control theory.     

Regime diagram of the development of long-wave near-wall disturbances in a hypersonic boundary layer

A regime diagram of the development of slow near-wall disturbances induced by an unsteady self-induced pressure perturbation in a hypersonic boundary layer is constructed for a disturbance wavelength greater than the boundary layer thickness. It is shown that the main factors shaping the perturbed flow are the gas enthalpy near the body surface, the intensity of the viscous-inviscid interaction, and the nature (sub- or supersonic) of the main part of the boundary layer. Nonlinear boundary-value problems are formulated for regimes in which the near-wall boundary layer region plays a decisive role. Numerical and analytical solutions are obtained in the linear approximation. It is shown that intensification of the viscous-inviscid interaction or an increase in the role of the supersonic main region of the boundary layer impart generally supersonic properties to the main part of the boundary layer, i.e. the upstream propagation of the disturbances is damped and the disturbance growth downstream becomes more intense. Damping of the viscous-inviscid interaction and an increase in the role of the subsonic main part of the boundary layer have the opposite effect. Surface cooling increases the effect of the main part of the boundary layer on the formation of pressure disturbances and surface heating leads to an increase in the effect of the near-wall boundary layer region. It is also shown that for the regimes considered disturbances propagate in a direction opposite to that of the free stream from the turbulent flow region located downstream of the local disturbance development region.Translated from Izvestiya Rossiiskoi Academii Nauk, Mekhanika Zhidkosti i Gaza, No. 6, 2004, pp. 59–71. Original Russian Text Copyright © 2004 by Bogolepov and Neiland.